2009
(92) Star-shaped Ssilacyclobutene-containing π-systems: synthesis and optical properties
Junhui Liu, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Organometallic 2009, 28, 413-417.
(93) 1-lithio-1,3-dienes as useful building blocks in organic synthesis
Wen-Xiong Zhang, and Zhenfeng Xi*
Pure and Applied Chemistry 2009, 81, 235-246.
(94) Alkyl aluminum catalyzed addition of amines to carbodiimides: a highly efficient route to substituted guanidines
Wen-Xiong Zhang,* Dongzhen Li, Zitao Wang, and Zhenfeng Xi*
Organometallic 2009, 28, 882-887.
(95) Zirconocene-mediated ligand-switched selective cleavage of active and inert carbon-carbon bonds in allylcyclopropanes
Chao Wang, Liang Deng, Jun Yan, Hailin Wang, Qian Luo, and Zhenfeng Xi*
Chem. Commun. 2009, 4414-4416.
(96) Skeletal rearrangement of all-carbon spiro skeletons mediated by Lewis acid
Fei Zhao, Chao Wang, Lantao Liu, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Commun. 2009, 6569-6571.
(97) Efficient ruthenium-catalyzed synthesis of [3]dendralenes from 1,3-dienic allylic carbonates
Kassem Beydoun, Hui-Jun Zhang, Basker Sundararaju, Bernard Demerseman, Mathieu Achard, Zhenfeng Xi, Christian Bruneau*
Chem. Commun. 2009, and 6580-6582.
(98) 硅杂四元环化合物的合成和反应
刘俊辉, 张文雄, 席振峰*
有机化学, 2009, 29, 491-503.
(99) 硅杂六元环化合物的合成*
刘俊辉, 张韶光, 张文雄, 席振峰*
化学进展, 2009, 21, 1475-1486.
(100) 硅杂六元环化合物的反应*
张韶光, 刘俊辉, 张文雄, 席振峰*
化学进展, 2009, 21, 1487-1493.
(101) Ruthenium-catalyzed nucleophilic allylic substitution reactions from β-silylated allylic carbonates
Hui-Jun Zhang, Bernard Demerseman, Loic Toupet, Zhenfeng Xi,* and Christian Bruneau*
Organometallics 2009, 28, 5173-5182.
(102) Synthesis of functionalized siloles from Si-tethered diynes
Qian Luo, Li Gu, Chao Wang, Junhui Liu, Wen-xiong Zhang, and Zhenfeng Xi*
Tetrahedron Lett. 2009, 50, 3213-3215.（创刊五十周年邀请论文）
(103) 协同效应：双金属有机化合物及Lewis酸促进的金属有机化学反应
席振峰*
中国科学B辑：化学2009, 39, 1115-1124.（国庆六十周年专辑邀请评述）
(104) Hydride-induced novel cyclization of dienedinitriles leading to multi-functionalized cyclopentadienes
Hui-jun Zhang, Tianhao Meng, Bernard Demerseman, Christian Bruneau,* Zhenfeng Xi*
Org. Lett. 2009, 11, 4458-4461.
(105) Ruthenium catalysts for structurally controlled mono- and bis-allylation of active methylene compounds with aliphatic allylic substrates
Hui-Jun Zhang, Bernard Demerseman, Zhenfeng Xi,* and Christian Bruneau*
Adv. Synth. Catal. 2009, 351, 2724-2728.
(106) Hydride-induced cleavage of C-O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application
Qifeng Wang, Lantao Liu, Chen Lin, Hui Sun, Wen-xiong Zhang, and Zhenfeng Xi*
Dalton Trans. 2009, 10433-10435.
(107) Zirconium- and silicon-containing intermediates with three fused rings in a zirconocene-mediated intermolecular coupling reaction
Wen-Xiong Zhang, Shaoguang Zhang, Xiaohua Sun, Masayoshi Nishiura, Zhaomin Hou,* and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2009, 48, 7227-7231.
(108) Isolation, structural characterization and synthetic application of oxy-cyclopentadienyl dianions
Lantao Liu, Wen-Xiong Zhang, Chao Wang, Congyang Wang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2009, 48, 8111-8114.
(109) Efficient one-pot synthesis of 2,3-dihydropyrimidinthiones via multicomponent coupling of terminal alkynes, elemental sulfur and carbodiimides
Zitao Wang, Yang Wang, Wen-Xiong Zhang,* Zhaomin Hou, and Zhenfeng Xi*
J. Am. Chem. Soc. 2009, 131, 15108-15109.
(110) One-pot multi-component synthesis of azaindoles and pyrroles from one molecule of Si-tethered diyne and three or two molecules of organonitriles mediated by zirconocence
Shaoguang Zhang, Xiaohua Sun, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Eur. J. 2009, 15, 12608-12617.
2010
(111) Isolation and X-ray structure of a trimeric 1,4-dilithio-1,3-butadiene and a dimeric Me3Si-substituted 1,4-dilithio-1,3-butadiene
Lantao Liu, Wen-Xiong Zhang,* Qian Luo, Heng Li, and Zhenfeng Xi*
Organometallics 2010, 29, 278-281.
(112) Zn(OTf)2-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn–N amido species
Dongzhen Li, Jie Guang, Wen-Xiong Zhang,* Yang Wang, and Zhenfeng Xi*
Org. Biomol. Chem. 2010, 8, 1816-1820.
(113) Formation of α-lithio siloles from silylated 1,4-dilithio-1,3-butadienes: mechanism and applications
Qian Luo, Chao Wang,Li Gu, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Asian J. 2010, 5, 1120-1128.
(114) 金属杂六元环的合成方法研究进展
王奇峰, 林辰, 席振峰*
有机化学（综述与进展） 2010, 30, 157-166.（综述文章）
(115) Efficient one-pot synthesis of N-containing heterocycles by multi-component coupling of silicon-tethered diynes, nitriles and isocyanides via intramolecular cyclization of iminoacyl-Zr intermediates
Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Eur. J. 2010, 16, 8419-8426.
(116) Advances in the synthesis and reactivity of 2-pyranylidene carbene complexes
Qifeng Wang, Wen-xiong Zhang, Chen Lin, and and Zhenfeng Xi*
Chin. Sci. Bull. 2010, 55, 2915-2923.
(117) Cleavage and re-organization of Zr-C/Si-C bonds leading to Zr/Si-N organometallic and heterocyclic compounds
Shaoguang Zhang, Wen-Xiong Zhang, Jin Zhao, and Zhenfeng Xi*
J. Am. Chem. Soc. 2010, 132, 14042-14045.
(118) 1,4-dilithio-1,3-dienes: reaction and synthetic applications
Zhenfeng Xi*
Acc. Chem. Res. 2010, 43, 1342-1351.
(119) Selective synthesis of dibenzo[a,c]cyclooctatetraenes via palladium-catalyzed [4+4] cyclic homocoupling of borylvinyl iodobenzene derivatives
Hui-jun Zhang, Junnian Wei, Fei Zhao, Yun Liang, Zitao Wang, and Zhenfeng Xi*
Chem. Commun. 2010, 46, 7439-7441.
2011
(120) Facile one-pot construction of polycyclic frameworks using a synergistic Diels–Alder reaction, ene reaction, and allylation reaction strategy
Dongzhen Li, Yang Cao, An Shi, and Zhenfeng Xi*
Chem. Asian J. 2011, 6, 392 – 395.
(121) One-pot selective syntheses of 5-azaindoles through zirconocene-mediated multicomponent reactions with three different nitrile components and one alkyne component
Shaoguang Zhang, Wen-Xiong Zhang, Jing Zhao, and Zhenfeng Xi*
Chem. Eur. J. 2011, 17, 2442-2449.
(122) One-pot synthesis of pyrrolo[3,2-d]pyridazines and pyrrole-2,3-diones via zirconocene-mediated four-component coupling of Si-tethered diyne, nitriles and azide
Shaoguang Zhang, Jing Zhao, Wen-Xiong Zhang, and Zhenfeng Xi*
Org. Lett. 2011, 13, 1626-1629.
(123) Silyl-substituted 1,3-butadienes for Diels–Alder reaction, ene reaction and allylation reaction
Fei Zhao, Shaoguang Zhang, and Zhenfeng Xi*
Chem. Commun. 2011, 47, 4348-4357. (Feature Article)
(124) Iterative dianion relay along the ring: formation of gem-bis(trimethylsilyl) cyclopentenones from 2,5-bis(trimethylsilyl) oxy-cyclopentadienyl dianions and acid chlorides
Heng Li, Lantao Liu, Zitao Wang, Fei Zhao, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Eur. J. 2011, 17, 7399-7403.
(125) Ln4(CH2)4-cubane-type rare-earth methylidene complexes consisting of “(C5Me4SiMe3)LnCH2” units (Ln = Tm, Lu)
Wen-Xiong Zhang, Zitao Wang, Masayoshi Nishiura, Zhenfeng Xi,* and Zhaomin Hou*
J. Am. Chem. Soc. 2011, 133, 5712-5715.
(126) Palladium-catalyzed, one-pot, three-component approach to alpha-alkynyl indoles from o-bromo-(2,2-dibromovinyl)benzenes, terminal alkynes and arylamines
Yun Liang, Tianhao Meng, Hui-Jun Zhang, and Zhenfeng Xi*
Synlett 2011, 911-914.
(127) Palladium-catalyzed synthesis of benzosilolo[2,3-b]indoles via cleavage of a C(sp(3))-Si bond and consequent intramolecular C(sp(2))-Si coupling
Yun Liang, Shaoguang Zhang, and Zhenfeng Xi*
J. Am. Chem. Soc. 2011, 133, 9204-9207.
(128) Formation of zirconocenes containing vinyl-imine and keteniminate species from zirconacycles and diphenylacetonitrile
Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang,* and Zhenfeng Xi*
Organometallics 2011, 30, 3464-3467.
(129) Zirconocene and Si-tethered diynes: a happy match directed toward organometallic chemistry and organic dynthesis
Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi*
Acc. Chem. Res. 2011, 44, 541-551.
(130) Opening the dilole ting: rfficient and dpecific vleavage of the endo-C(sp2)-Si bond with AcOH/ROH system
Qian Luo, Chao Wang, Yuexing Li, Kunbing Ouyang, Li Gu, Masanobu Uchiyama, and Zhenfeng Xi*
Chem. Sci. 2011, 2, 2271-2274.
(131) Procedure-Ccontrolled selective synthesis of 5-acyl-2-iminothiazolines and their selenium and tellurium derivatives by convergent tandem annulation
Yang Wang, Wen-Xiong Zhang,* Zitao Wang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2011, 50, 8122-8126.
(132) Cross-coupling of aryl/alkenyl silyl ethers with grignard reagents through nickel-catalyzed CO bond activation
Fei Zhao, Da-Gang Yu, Ru-Yi Zhu, Zhenfeng Xi,* and Zhang-Jie Shi*
Chem. Lett. 2011, 40, 1001-1003.
(133) One-pot synthesis and unpredicted hydrogen bonds of the guanidinium triflates from readily available amines, carbodiimides, and Zn(OTf)2
Organometallics 2011, 30, 5278-5283.
(134) Synthesis of benzothiophene derivatives from dilithio reagents, sulfur, and electrophiles via electrophilic cyclization
Zitao Wang, Weizhi Geng, Hanliu Wang, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Tetrahedron Lett. 2011, 52, 6997-6999.
2012
(135) Regioselective ring expansion of 2,4-diiminoazetidines via cleavage of C−N and C(sp3)−H bonds: efficient construction of 2,3-dihydropyrimidinesulfonamides
Yang Wang, Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi*
J. Am. Chem. Soc. 2012, 134, 2926-2929.
(136) Palladium-catalyzed Silyl C(sp3)-H bond activation
Yun Liang, Weizhi Geng, Junnian Wei, and Zhenfeng Xi*
Org. Biomol. Chem. 2012, 10, 1537-1542.
(137) Palladium-catalyzed intermolecular coupling of 2-silylaryl bromides with alkynes: synthesis of benzosiloles and heteroarene-fused siloles by catalytic cleavage of the C(sp3)-Si bond
Yun Liang, Weizhi Geng, Junnian Wei, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2012, 51, 1934-1937.
(138) Synthesis of benzothieno[2,3-b]thiophenes, [2,3-b:3',2'-d]-dithienothiophenes and their selenium derivatives via electrophilic cyclization and McMurry cyclization
Weizhi Geng, Hanliu Wang, Zitao Wang, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Tetrahedron 2012, 68, 5283-5289.
(139) Carbonylation of 1-lithiobutadiene with carbon monoxide followed by intramolecular acyllithiation of C=C double bond and intermolecular acylation with acid chloride: scope, applications, and mechanistic aspects
Heng Li, Lantao Liu, Fei Zhao, Congyang Wang, Chao Wang, Qiuling Song, Wen-Xiong Zhang, and Zhenfeng Xi*
J. Org. Chem. 2012, 77, 4793-4800.
(140) Pd-catalyzed intermolecular tandem reaction of gem-dibromoenynes with anilines: a one-pot synthesis of quinolines and quinolinones
Tianhao Meng, Wen-Xiong Zhang, Hui-Jun Zhang, Yun Liang, and Zhenfeng Xi*
Synthesis 2012, 44, 2754-2762.
(141) Synthesis of gem-dihaloenynes and butatrienes from gem-dihalovinyl derivatives
Tianhao Meng, Hui-Jun Zhang, and Zhenfeng Xi*
Tetrahedron Lett. 2012, 53, 4555-4557.
(142) Metal-free synthesis of cyclic di-oxoguanidines via one-pot sequential transforamtion of amines, carbodiimides and acid dichlorides
Fei Zhao, Yang Wang, Wen-Xiong Zhang,* and Zhenfeng Xi*
Org. Biomol. Chem. 2012, 10, 6266-6270. (Inside Front Cover)
(143) 1,3-Butadienylzinctrimer formed via transmetallation from 1,4-dilithio-1,3-butadienes: synthesis, structural characterization and application in negishi cross-coupling
Yi Zhou, Wen-Xiong Zhang, and Zhenfeng Xi*
Organometallics 2012, 31, 5546-5550.
(144) 2,6-Diazasemibullvalenes: synthesis, structural characterization, reaction chemistry and theoretical analysis
Shaoguang Zhang, Junnian Wei, Ming Zhan, Qian Luo, Chao Wang, Wen-Xiong Zhang, and Zhenfeng Xi*
J. Am. Chem. Soc. 2012, 134, 11964-11967. (JACS Spotlight)
(145) Construction of benzosiloles, 6 and 8-membered silacyclic skeletons via Pd-catalyzed intramolecular mizoroki-heck reaction of vinylsilanes
Kunbing Ouyang, Yun Liang, and Zhenfeng Xi*
Org. Lett. 2012, 14, 4572-4575.
(146) Rare-earth metal tri(trimethylsilylmethyl) anionic complexes bearing one 1-phenyl-2,3,4,5-tetrapropylcyclopentadienyl ligand: synthesis, structural characterization and application
Ling Xu, Zitao Wang, Wen-Xiong Zhang,* and Zhenfeng Xi*
Inorg. Chem. 2012, 51, 11941-11948.
(147) Reactivity of seven-membered azazirconacycloallenes and four-membered zirconacycles towards diphenylacetonitrile
Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang,* Zhenfeng Xi*
Organometallics 2012, 31, 8370-8374.
(148) Palladium/phosphine-cyclopentadiene-catalyzed selective cleavage of C-N bonds in secondary amines: synthesis of pyrrole and indole derivatives from secondary amines and alkenyl or aryldibromides
Weizhi Geng, Wen-Xiong Zhang, Wei Hao, and Zhenfeng Xi*
J. Am. Chem. Soc. 2012, 134, 20230-20233.
2013
(149) Synthesis, characterization, and reactivity of N-Acyl chloroformamidines: useful building blocks for the construction of N-Acyl- substituted 1,1-diaminoethylenes, amidines, ureas, and thioureas
Yang Wang, Yue Chi, Fei Zhao, Wen-Xiong Zhang,* and Zhenfeng Xi
Synthesis 2013, 45, 347-354.
(150) 碱在过渡金属催化的有机化学反应中的作用
欧阳昆冰 席振峰*
化学学报 2013, 71, 13-25.（综述文章）
(151) Construction of octa-alkyl substituted and deca-substituted all-cis octatetraenes via linear dimerization of 1,4-dicopper-1,3-butadienes and subsequent cross-coupling with halides
Junnian Wei, Zitao Wang, Wen-Xiong Zhang, and Zhenfeng Xi*
Org. Lett. 2013, 15, 1222-1225
(152) Lewis acid-catalyzed site-selective cycloadditions of 2,6-diazasemibullvalenes with isocyanides, azides and diazo compounds for the synthesis of diaza- and triaza-brexadiene derivatives
Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2013, 3485-3489.
(153) DFT studies on the reaction mechanisms of 1,4-dilithio-1,3-dienes with nitriles affording pyridines and 1,3,5-triazines
Fei Zhao, Ming Zhan, Wen-Xiong Zhang, and Zhenfeng Xi*
Organometallics 2013, 52, 3485.
(154) Barium Dibenzopentalenide as a Main-Group Metal η8 Complex: Facile Synthesis from 1,4-Dilithio-1,3-butadienes and Ba[N(SiMe3)2]2, Structural Characterization, and Reaction Chemistry
Heng Li, Baosheng Wei, Ling Xu, Wen-Xiong Zhang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2013, 52, 10822-10825.
(155) Oxidation of C-H bonds to C=O bonds by O2 only or N-oxides and DMSO: synthesis of Δ1-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes
Shaoguang Zhang, Ming Zhan, Qian Luo, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Commun. 2013, 49, 6146-6148.
(156) 1,2,3,4-Tetrasubstituted Cyclopentadienes and Their Applications for Metallocenes: Efficient Synthesis through Zirconocene- and CuCl-Mediated Intermolecular Coupling of Two Alkynes and One Diiodomethane
Weizhi Geng, Chao Wang, Jie Guang, Wei Hao, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Eur. J. 2013, 19, 8657-8664.
(157) Mechanistic Study on the Cleavage and Reorganization of C(sp3)-H and C=N Bonds in Carbodiimides: Synthesis of 1,2-Dihydrothiopyrimidines and 2,3-Dihydropyrimidinthiones through Four-Component Coupling
Yang Wang, Fei Zhao, Yi Zhou, Yue Chi, Zitao Wang, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Eur. J. 2013, 19, 10643-10654.
(158) Alkaline Earth Metallocenes Coordinated with Ester Pendants: Synthesis, Structural Characterization, and Application in Metathesis Reactions
Heng Li, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Eur. J. 2013, 19, 12859-12866.
(159) Half-sandwich bis(propiolamidinate) rare-earth metal complexes: synthesis, structure and dissociation of the cyclopentadienyl ligand via competition with an amidinate
Ling Xu, Yu-Chen Wang, Wen-Xiong Zhang* and Zhenfeng Xi
Dalton Trans. 2013, 42, 16466-16469.
(160) Programmed Selective sp2 C-O Bond Activation toward Multiarylated Benzenes
Fei Zhao, Yun-Fei Zhang, Jing Wen, Da-Gang Yu, Jiang-Bo Wei, Zhenfeng Xi* and Zhang-Jie Shi*
Org. Lett. 2013, 15, 3230-3233.
(161) Diazo Compounds as Electrophiles To React with 1,4-Dilithio-1,3-dienes: Efficient Synthesis of 1‑Imino-pyrrole Derivatives
Ming Zhan, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Org. Lett. 2013, 15, 4182-4185.
(162) DFT Studies on the Reaction Mechanisms of 1,4-Dilithio 1,3-Dienes with Nitriles
Fei Zhao, Ming Zhan, Wen-Xiong Zhang, and Zhenfeng Xi*
Organometallics 2013, 32, 2059-2068.
(163) 3‑D Brick-Wall Polymeric Structure of TMEDA-Supported 1,4-Dilithio-1,3-Butadiene
Shaoguang Zhang, Ming Zhan, Wen-Xiong Zhang*, and Zhenfeng Xi*
Organometallics 2013, 32, 4020-4023.
(164) Palladium-catalyzed cleavage of the Me–Si bond in ortho-trimethylsilyl aryltriflates: synthesis of benzosilole derivatives from ortho-trimethylsilyl aryltriflates and alkynes
Tianhao Meng, Kunbing Ouyang, and Zhenfeng Xi*
RSC Adv. 2013, 3, 14273-14276.
2014
(165) Magnesiacyclopentadienes as Alkaline-Earth Metallacyclopentadienes: Facile Synthesis, Structural Characterization, and Synthetic Application
Junnian Wei, Liang Liu, Ming Zhan, Ling Xu, Wen-Xiong Zhang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2014, 53, 5634-5638.
(166) Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-β-Hydrogen Atoms
Wei Hao, Junnian Wei, Weizhi Geng, Wen-Xiong Zhang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2014, 53, 14533-14537.
(167) Cleavage of the C=N Bond in Carbodiimides via Release of High Ring Strain: A New Strategy for the Selective Synthesis of 2-Aminoaryl Alkynyl Imines
Yi Zhou, Yue Chi, Fei Zhao, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Eur. J. 2014, 20, 2463-2468.
(168) Palladium-Catalyzed One-Pot Three- or Four-Component Coupling of Aryl Iodides, Alkynes, and Amines through C-N Bond Cleavage: Efficient Synthesis of Indole Derivatives
Wei Hao, Weizhi Geng, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Eur. J. 2014, 20, 2605-2612.
(169) Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Δ1-Bipyrroline Derivatives
Shaoguang Zhang, Ming Zhan, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Eur. J. 2014, 20, 9744-9752.
(170) Coordination-induced skeletal rearrangements of zirconacyclobutene–silacyclobutene fused complexes
Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Coord. Chem. Rev. 2014, 270−271, 2−13.（综述文章）
(171) Weizhi Geng, Junnian Wei, Wen-Xiong Zhang, and Zhenfeng Xi* Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry
Weizhi Geng, Junnian Wei, Wen-Xiong Zhang, and Zhenfeng Xi*
J. Am. Chem. Soc. 2014, 136, 610-613.
(172) Substituent-Controlled Selective Synthesis of N‑Acyl 2‑Aminothiazoles by Intramolecular Zwitterion-Mediated C−N Bond Cleavage
Yang Wang, Fei Zhao, Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi
J. Org. Chem. 2014, 79, 11146-11154.
(173) Mechanistic Insights into N-N Bond Cleavage in Catalytic Guanylation Reactions between 1,2-Diarylhydrazines and Carbodiimides
Ling Xu, Yu-Chen Wang, Wangyang Ma, Wen-Xiong Zhang,* and Zhenfeng Xi*
J. Org. Chem. 2014, 79, 12004-12009.
(174) Intramolecular C–F and C–H bond cleavage promoted by butadienyl heavy Grignard reagents
Heng Li, Xiao-Ye Wang, Baosheng Wei, Ling Xu, Wen-Xiong Zhang, Jian Pei, and Zhenfeng Xi*
Nat. Commun. 2014, 5, 4508-4517.
(175) Selective synthesis of (Z)-2-enynyl-2-hydroxyimidazolidine-4,5-diones via Cu(I)-mediated multicomponent coupling of terminal alkynes, carbodiimides and oxalyl chloride
Fei Zhao, Yuexing Li, Yang Wang, Wen-Xiong Zhang,* and Zhenfeng Xi
Org. Biomol. Chem. 2014, 12, 3336-3339.
(176) Synthesis of semibullvalene derivatives via Co2(CO)8-mediated cyclodimerization of 1,4-dilithio-1,3-butadienes
Shaoguang Zhang, Ming Zhan, Qifeng Wang, Chao Wang, Wen-Xiong Zhang, and Zhenfeng Xi*
Org. Chem. Front. 2014, 1, 130-134.
(177) Synthesis and applications of 1-iodo-4-MgCl-1,3-dienes and 1-iodovinyl phenylmagnesium chlorides
Junnian Wei, Yongliang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Org. Chem. Front. 2014, 1, 983-987.
(178) Organometallic intermediate-based organic synthesis: organo-di-lithio reagents and beyond
Wen-Xiong Zhang and Zhenfeng Xi*
Org. Chem. Front. 2014, 1, 1132-1139.（综述文章）
(179) Oxidant-Switchable Selective Synthesis of 2‑Aminobenzimidazoles via C−H Amination/Acetoxylation of Guanidines
Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi
Org. Lett. 2014, 16, 6274-6277.
(180) Reaction of Titanacyclobutene–Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C–N Triple Bond of Nitrile into the Silacyclobutene Ring
Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi
Organometallics 2014, 33, 8-11.
(181) Cyclopentadienyl-Like Ligand as a Reactive Site in Half-Sandwich Bis(amidinato) Rare-Earth-Metal Complexes: An Efficient Application in Catalytic Addition of Amines to Carbodiimides
Peng-Hui Wei, Ling Xu, Li-Cheng Song,* Wen-Xiong Zhang,* and Zhenfeng Xi*
Organometallics 2014, 33, 2784-2789.
(182) Novel reactivities of 2,2-dichloroimidazolidine-4,5-diones: synthesis of copper(I) diamidocarbene complex, 2-thioxo/selenoxoimidazolidine-4,5-dione, and 2,2-difluoroimidazolidine-4,5-dione
Fei Zhao, Yang Wang, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi
Tetrahedron Lett. 2014, 55, 4597-4600.
2015
(183) Recent development of synthetic preparation methods for guanidines via transition metal catalysis
Wen-Xiong Zhang,* Ling Xu, and Zhenfeng Xi
Chem. Commun. 2015, 51, 254-265.（综述文章）
(184) Efficient Synthesis of Aza-triquinacene Derivatives via Cycloaddition of 2,6-Diazasemibullvalenes with Nitroso Compounds
Ming Zhan, Shaoguang Zhang, Zhe Huang, and Zhenfeng Xi*
Chem. Asian J. 2015, 10, 862-864.
(185) Pd-catalyzed Cyclodimerization of Alkenyl and Aryl Dibromides: Construction of Dibenzo[a,e]cyclooctatetraenes
Kunbing Ouyang and Zhenfeng Xi*
Chin. J. Cat. 2015, 36, 24-32. (Special Issue on Catalysis in Organic Synthesis)
(186) Synthesis of triarylmethanols via tandem arylation/oxidation of diarylmethanes
Jianyou Mao, Kelly Eberle, Jiadi Zhang, Carles Rodríguez-Escrich, Zhenfeng Xi,* Miquel A. Pericàs,* and Patrick J. Walsh*
Tetrahedron Lett. 2015, 56, 3604-3607.
(187) Synthesis of α,α,α,α-Tetrachloro Δ1-bipyrrolines and 4,8-Dichloro 2,6-diazasemibuvallenes
Ming Zhan, Shaoguang Zhang, Zhe Huang, and Zhenfeng Xi*
Org. Lett. 2015, 17, 1026-1029.
(188) Dianions as Formal Oxidants: Synthesis and Characterization of Aromatic Dilithionickeloles from 1,4-Dilithio-1,3-butadienes and Ni(COD)2
Junnian Wei, Wen-Xiong Zhang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2015, 54, 5999-6002.
(189) Synthesis, Structural Characterization, and Reactivity of a Fluorene-Based Calcium Oxycyclopentadienide Complex
Baosheng Wei, Heng Li, Wen-Xiong Zhang,* and Zhenfeng Xi*
Organometallics 2015, 34, 1339-1344.
(190) The First Lutetacyclopentadienes: Synthesis, Structure and Diversified Insertion/C−H Activation Reactivity
Ling Xu, Yu-Chen Wang, Junnian Wei, Yang Wang, Zitao Wang, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Eur. J. 2015, 21, 6686-6689. (Hot paper and Highlighted by ChemistryViews)
(191) Mechanistic Considerations of the Catalytic Guanylation Reaction of Amines with Carbodiimides for Guanidine Synthesis
Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi
Organometallics 2015, 34, 1787-1801.（综述文章）
(192) Half-Sandwich Complexes of DyIII: A Janus-Motif with Facile Tunability of Magnetism
Shan-Shan Liu, Ling Xu, Shang-Da Jiang, Yi-Quan Zhang, Yin-Shan Meng, Zitao Wang, Bing-Wu Wang,* Wen-Xiong Zhang,* Zhenfeng Xi, and Song Gao*
Inorg. Chem. 2015, 54, 5162-5168.
(193) Semibullvalene and Diazasemibullvalene: Recent Advances in the Synthesis, Reaction Chemistry, and Synthetic Applications
Shaoguang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Acc. Chem. Res. 2015, 48, 1823-1831.
(194) Synthesis and Mechanistic Study of Cyclic Oxoguanidines via Zn(OTf)2-Catalyzed Guanylation/Amidation from Readily Available Amino Acid Esters and Carbodiimides
Yue Chi, Ling Xu, Shanshan Du, Haihan Yan, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Eur. J. 2015, 21, 10369-10378. (Cover Paper)
(195) 1,3-Butadienyl Dianions as Non-innocent Ligands: Synthesis and Characterization of Aromatic Dilithio Rhodacycles
Junnian Wei, Yongliang Zhang, Wen-Xiong Zhang, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2015, 54, 9986-9990. (Very Important Paper)
(196) Reaction of Dilithio Reagents with PhSiH3: Formation of Siloles and 3-Silacyclopentenes
Baosheng Wei, Heng Li, Jianhao Yin, Wen-Xiong Zhang, and Zhenfeng Xi*
J. Org. Chem. 2015, 80, 8758-8762.
(197) Well-defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization
Liang Liu, Weizhi Geng, Qi Yang, Wen-Xiong Zhang, and Zhenfeng Xi*
Organometallics 2015, 34, 4198-4201.
(198) Combining Pd(p-allyl)Cp and PPh3 as a unique Catalyst for Efficient Synthesis of Alkyliodo Indoles via C(sp3)-I Reductive Elimination
Wei Hao, Han Wang, Patrick J. Walsh* and Zhenfeng Xi*
Org. Chem. Front. 2015, 2, 1080-1084.
(199) Lithium Aluminate Complexes and Alumoles from 1,4-Dilithio-1,3-Butadienes and AlEt2Cl
Yongliang Zhang, Junnian Wei, Wen-Xiong Zhang, and Zhenfeng Xi*
Inorg. Chem. 2015, 54, 10695-10700.
(200) Cyclopentadiene-Phosphine/Palladium Catalyzed Synthesis of Indolizines from Pyrrole and 1,4-Dibromo-1,3-butadienes
Wei Hao, Han Wang, Qingyu Ye, Wen-Xiong Zhang, and Zhenfeng Xi*
Org. Lett. 2015, 17, 5674-5677.
(201) Transition-Metal-Catalyzed Cleavage of C−N Single Bonds
Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Rev. 2015, 115, 12045-12090.（综述文章）
(202) Insertion/Rearrangement Reactivity of a Lutetacyclopentadiene towards N,N-Diphenylcarbodiimide: Cooperative Effect of the Metal Center, Concentration of LiCl, and Solvent
Ling Xu, Junnian Wei, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Eur. J. 2015, 21, 15860-15866.
(203) Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines
Wangyang Ma, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi
New J. Chem. 2015, 39, 7649-7655.
2016
(204) Aromatic Dicupra[10]annulenes
Junnian Wei, Yongliang Zhang, Yue Chi, Liang Liu, Wen-Xiong Zhang, and Zhenfeng Xi*
J. Am. Chem. Soc. 2016, 138, 60-63.
(205) Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation
Ling Xu, Yang Wang, Yu-Cheng Wang, Zitao Wang, Wen-Xiong Zhang,* and Zhenfeng Xi
Organometallics 2016, 35, 5-8.
(206) A DFT Study on Conversion of Aryl Iodides to Alkyl Iodides: Reductive Elimination of R–I from Alkylpalladium Iodide Complexes with Accessible β-Hydrogens
Wei Hao, Junnian Wei, Yue Chi, Patrick J. Walsh,* and Zhenfeng Xi*
Chem. Eur. J. 2016, 22, 3422-3429.
(207) Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes
Baosheng Wei, Heng Li, Wen-Xiong Zhang*, and Zhenfeng Xi*
Organometallics 2016, 35, 1458-1463.
(208) Direct Synthesis of Phospholyl Lithium from White Phosphorus
Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang,* and Zhenfeng Xi
Angew. Chem. Int. Ed. 2016, 55, 9187-9190.
(209) Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts
Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*
Angew. Chem. Int. Ed. 2016, 55, 14762-14765.
2017
(210) Formation of Cyclopenta[c]pyridine Derivatives from 2,5-Disubstituted Pyrroles and 1,4-Dibromo-1,3-butadienes via Pyrrole-Ring One-Carbon Expansion
Jianhao Yin, Qingyu Ye, Wei Hao, Shuaijing Du, Yucheng Gu, Wen-Xiong Zhang,* and Zhenfeng Xi*
Org. Lett. 2017, 19, 138-141.
(211) CuOTf-Catalyzed Selective Generation of 2-Aminopyrimidines from Carbodiimides and Diaryliodonium Salts via Triple C(sp3)‒H Functionalization
Yue Chi, Haihan Yan, Wen-Xiong Zhang,* and Zhenfeng Xi*
Chem. Eur. J. 2017, 23, 757-761. (Cover Paper)
(212) Metallacyclopentadienes: Synthesis, Structure and Reactivity
Wangyang Ma, Chao Yu, Tianyang Chen, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Soc. Rev. 2017, 46, 1160-1192.
(213) Spiro Metalla-aromatics of Pd, Pt, Rh: Synthesis and Characterization
Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang,* and Zhenfeng Xi*
J. Am. Chem. Soc. 2017, 139, 5039-5042.
(214) Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4[O] Inverse Crown Ether Complex
Baosheng Wei, Liang Liu, Wen-Xiong Zhang,* and Zhenfeng Xi
Angew. Chem. Int. Ed. 2017, 56, 9188-9192.
(215) Synthesis of Quinoline Derivatives via Cu-Catalyzed Cascade Annulation of Heterocumulenes, Alkynes, and Diaryliodonium Salts
Yue Chi, Haihan Yan, Wen-Xiong Zhang,* and Zhenfeng Xi
Org. Lett. 2017, 19, 2694-2697.
(216) Aromatic Tetralithiodigalloles with a Ga–Ga Bond: Synthesis and Structural Characterization
Yongliang Zhang, Yue Chi, Junnian Wei, Qi Yang, Zhenqiang Yang, Hui Chen, Ruina Yang,* Wen-Xiong Zhang,* and Zhenfeng Xi*
Organometallics 2017, 36, 2982-2986.
(217) Synthesis of Dibromo- and Tetrabromo-bipyrrolines and their Corresponding 2,6-Diazasemibuvallene Derivatives
Zhe Huang, Ming Zhan, Shaoguang Zhang, Qian Luo, Wen-Xiong Zhang* and Zhenfeng Xi*
Org. Chem. Front. 2017, 4, 1785-1788.
(218) 从氮气直接合成含氮有机化合物
李嘉鹏, 殷剑昊, 俞超, 张文雄, 席振峰*
化学学报, 2017, 75, 733-743.（封面）（综述文章）
(219) Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes
Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi
Chem. Sci. 2017, 8, 6852-6856.
(220) Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation
Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang,* and Zhenfeng Xi*
J. Am. Chem. Soc. 2017, 139, 13688−13691.
(221) Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes
Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang*
Angew. Chem. Int. Ed. 2017, 56, 15886–15890.
2018
(222) 金(I)催化的萘环上三甲基硅基的1,2-迁移反应
杨琪, 刘亮, 张文雄, 席振峰*
有机化学 2018, 38, 272-276.
(223) The Aromatic Dianion Metalloles
Junnian Wei,* Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Sci. 2018, 9, 560-568. (Perspective)
(224) Lewis Acid-Promoted Ring-Contraction of 2,4,6,8-Tetrasubstituted 1,5-Diazacyclooctatetraenes to 2,4,6-Trisubstituted Pyridines
Zhe Huang, Wen-Xiong Zhang, and Zhenfeng Xi*
Org. Lett. 2018, 20, 485-488.
(225) Rhodium-catalyzed intramolecular carbo-silylation of alkynes via C(sp3)-Si bond cleavage
Qi Yang, Liang Liu, Yue Chi, Wei Hao, Wen-Xiong Zhang* and Zhenfeng Xi*
Org. Chem. Front. 2018, 5, 860-863.
(226) Selective Transformation of Well-defined Alkenyllithiums to Alkenylmagnesiums via Transmetalation
Miaomiao Zhu, Liang Liu, Yongliang Zhang, Hai-Tao Yu, Wen-Xiong Zhang,* and Zhenfeng Xi*
Chem. Eur. J. 2018, 24, 3186-3191. (Cover Paper)
(227) The Aromatic Dianion Metalloles
Junnian Wei*, Wen-Xiong Zhang, and Zhenfeng Xi*
Chem. Sci. 2018, 9, 560–568.
(228) Diversified Aggregation States of Phospholyl Lithiums
Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi
Organometallics 2018, 37, 2018–2022.
(229) Well-defined Styryl and Biphenyl Calcium Complexes from Dilithio Compounds and Calcium Iodide: Synthesis, Structure and Reactivity toward Nitrous Oxide
Baosheng Wei, Wen-Xiong Zhang*, and Zhenfeng Xi*
Dalton Trans. 2018, 47, 12540–12545.
(230) Magnesium Compounds: Generation and Synthetic Application
Miaomiao Zhu, Liang Liu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi*
Chem. Eur. J. 2018, 24, 19122–19135. (Invited Minireview)
